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Partial Oxidation of Methanol over Silver
Angleščina
163 b
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Trda
109.19
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Adobe ePub DRM
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Mehka
27.14
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Formaldehyde production from methanol over silver§catalyst is a fast, exothermic process where dilution§is used to control heat release. These properties are§indicators of Process Intensification potential. The§process is run adiabatically and produces hydrogen§(currently left in the tail gas, which is burnt). To§investigate the possibility of using a combination of§heat exchange and a lower concentration of oxygen in§the feed stream to increase hydrogen selectivity§while maintaining the required formaldehyde yield, a§complete reaction mechanism is necessary. This book§combines a review of existing literature on the§mechanism of formaldehyde production over silver with§an extensive experimental investigation and§microkinetic modelling to give a clearer picture of§the reaction mechanism. It then outlines the pathways§and reaction species that require further§investigation. This information should be useful for§students and researchers looking at reactions over§silver catalyst.
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